If you aren't familiar with Google Hangouts, go to https://hangouts.google.com/ and login using your GAFE or Gmail account. From there you can connect with people by Messaging, Video Call, or Phone Call. Best of all, Google has now made Google Hangouts more accessible. The people you connect with no longer need a Google Account to join a Video Call (see this article). So all you have to do is create a Video Call (from https://hangouts.google.com or an event in Google Calendar) and share the link with your friend. They can then join the video call as a Guest.
If you're looking for ways to connect using Google Hangouts, here are a few suggestions:
If you're looking for someone to connect with, join the Google Hangouts in Education community on Google+. Post your request to connect to see if someone can join you.
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